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Formation of GeV, SiV, and NV Color Centers in Single Crystal Diamond Needles Grown by Chemical Vapor Depositionстатья
Информация о цитировании статьи получена из
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 14 августа 2019 г.
- Авторы: Malykhin Sergei, Mindarava Yuliya, Ismagilov Rinat, Orekhov Anton, Jelezko Fedor, Obraztsov Alexander
- Журнал: Physica Status Solidi (B): Basic Research
- Год издания: 2019
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- Первая страница: 1800721
- DOI: 10.1002/pssb.201800721
- Аннотация: Herein the color centers formation in diamond crystallites of pyramidal shape grown by chemical vapor deposition (CVD) is described. The individual crystallites are extracted from polycrystalline films grown on silicon substrates. The silicon‐vacancy (SiV), germanium‐vacancy (GeV), and nitrogen‐vacancy (NV) centers are created by introducing corresponding precursors from substrate material, gaseous nitrogen, and thermally evaporated germanium added during CVD. Some amount of NV centers detected in all types of the diamond crystallites is assigned to uncontrollable presence of nitrogen in the CVD reactor. The low temperature photoluminescence spectra indicate presence of ensembles of SiV centers in diamond structure. The SiV centers are concentrated predominantly at apexes of the diamond crystallites located at substrate surface. Intense growth of CN radicals in plasma‐activated gas environment during CVD process is detected after nitrogen gas addition. The crystallites obtained with the nitrogen addition demonstrate significant variation of their pyramid angle. The photoluminescence spectra of crystallites grown with nitrogen addition demonstrate increase of both negatively and neutrally charged states of NV color center. The GeV centers are created via thermal evaporation of pure Ge during CVD growth. The photoluminescence spectra of the crystallites grown with Ge addition demonstrate presence of GeV color centers ensemble.
- Добавил в систему: Малыхин Сергей Александрович