Bright luminescence of diamonds with Ge-V centersстатья
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Дата последнего поиска статьи во внешних источниках: 16 января 2019 г.
Аннотация:We report on the quantum yield (eta) and decay time (tau) measurements at room temperature for the bright red-orange (602 nm) luminescence from new germanium-vacancy (Ge-V) centers in nano- and microcrystalline diamonds synthesized at high pressure and high temperature. The values eta = 3 +/- 1% and tau = 6.2 +/- 0.2 ns were found. The Stokes shift measured as the energy difference between the maxima of the luminescence and luminescence excitation spectra is negligible. The relative intensity of the zero-phonon line constitutes up to 70% from the total intensity of the luminescence. Results of our ab initio DFT calculations for the ground-state electronic and vibrational structure of (Ge-V)(-) in diamond are presented and discussed.