Existence and stability of chemical compoundsстатья
Информация о цитировании статьи получена из
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Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:A thermodynamic approach is used to analyze the existence and stability of compounds with a low stability in binary systems. The proposed formulas for the variation of the thermodynamic properties of such compounds with composition allow one to predict the properties of existing stable and metastable phases from the known properties of other phases and to find the most probable compositions of the ’weak’ compounds in question. The results can be used to obtain missing or optimize available thermodynamic data and also to refine the composition of a phase in the phase diagram.