Structure of products of H-H and C-H bond activation by Ni atom, Ni-2 cluster, and Ni-porphyrin complex of Ni-2 clusterстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:New catalytic systems based on porphyrin complexes of Ni-2 cluster and capable of activating C-H and H-H bonds are proposed. DFT calculations showed that a Ni-2 cluster can coordinate Ni-porphyrin with a considerable gain in energy. The structures of the products of methane and hydrogen activation were discussed.