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NEUTRON POWDER DIFFRACTION STUDY AT ROOM-TEMPERATURE AND AT 10-K OF THE CRYSTAL-STRUCTURE OF THE 133-K SUPERCONDUCTOR HGBA2CA2CU3O8+DELTAстатья
Информация о цитировании статьи получена из
Scopus,
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 9 ноября 2013 г.
- Авторы: CHMAISSEM O., HUANG Q., ANTIPOV EV, PUTILIN SN, MAREZIO M., LOUREIRO SM, CAPPONI JJ, THOLENCE JL, SANTORO A.
- Журнал: Physica C: Superconductivity and its Applications
- Том: 217
- Номер: 3-4
- Год издания: 1993
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 265
- Последняя страница: 272
- DOI: 10.1016/0921-4534(93)90328-N
- Аннотация: The crystal structure of the superconductor HgBa2Ca2Cu3O8+delta has been determined by neutron powder diffraction techniques at room temperature and at 10 K. The compound crystallizes with the symmetry of space group P4/mmm and lattice parameters a=3.8501 (1), c=15.7837 (9) Angstrom. The structure is described by the sequence of layers: ...[(CuO2)(Ca)(CuO2)(BaO)(HgOdelta)(BaO)(CuO2)(Ca)]... The compound, prepared by a solid-state reaction between HgO and the precursor Ba2Ca2Cu3Ox at a pressure of 18 kbar and 880 degrees C, has an oxygen composition corresponding to delta=0.41 (2). This extra oxygen is located on the layer of the mercury atoms at the sites 1/2, 1/2, 1/2. The superconducting transition temperature for the as-prepared sample is T-c=133 K. No evidence has been found of orthorhombic distortions, nor for substitution of some of the Hg atoms by Cu. The copper and oxygen atoms of the layers (CuO2) are coplanar for the Z=0 (CuO2) plane and almost perfectly coplanar for the others. No phase transition occurs down to 10 K.
- Добавил в систему: Антипов Евгений Викторович