Synthesis and electrochemical properties of ruthenium(II) complexes with biquinoline-containing polyamic acids - Polybenzoxazinone prepolymersстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:New polyamic acids with biquinoline units in the backbone, which are prepolymers of polybenzoxazinones, as well as their metal-polymer complexes containing [Ru(bpy)(2)](2+), were prepared. The electronic structure of these polymers was studied with the use of cyclic voltammetry, electronic absorption spectroscopy, and quantum-chemical calculations, and the location sites of electronic changes upon electrochemical reduction and oxidation were determined.