Photonics of Bis(diethylaminobenzylidene)cyclopentanone and Its Analogue with the Bisazacrown Moiety in Acetonitrileстатья
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Дата последнего поиска статьи во внешних источниках: 6 апреля 2016 г.
Аннотация:Photoprocesses in bis(diethylaminobenzylidene)cyclopentanone (D1) and its bis(aza-18-crown-
6) derivative (D2) have been studied in acetonitrile. The absorption, fluorescence, and phosphorescence
spectra of D1 are similar to those of D2. Laser excitation of oxygen-free solutions of D1 and D2 leads to generation of a triplet state with a lifetime of. ~1 μs and two intermediate species with lifetimes of 100 μs and
longer than 1 s.