LIF intensity distribution as a deperturbation tool: application to the fully-mixed A(1)Sigma(+)-b(3)Pi complex of NaRbстатья
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Аннотация:The intensity distribution in the NaRb A(1)&USigma;(+)(v’(A) = 16, J’ = 30; v’(A) = 18, J’ = 66) ∼ b(3)&UPi; → X-1&USigma;(+)(v”(X) = 2÷ 44, J” = J’1) fluorescence series induced by diode laser excitation from the ground state have been measured and directly applied to restore adiabatic potential energy curve for the A-state of the fully-mixed A(1)&USigma;(+)-b(3)&UPi; complex. Relative intensities in the long non-diagonal A → X progressions have been proved to be much less influenced by strong spin-orbit interaction than the corresponding term values of the fully coupled A(1)&USigma;+-b(3)&UPi; complex. © 2004 Elsevier Ltd. All rights reserved.