The electrochemical approach to antioxidant activity assay of metal complexes with dipicolylamine ligand, containing 2,6-di-tert-butylphenol groups, based on electrochemical DPPH-testстатья

Статья опубликована в высокорейтинговом журнале

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Дата последнего поиска статьи во внешних источниках: 26 декабря 2015 г.

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1. 1-s2.0-S1572665715300278-main.pdf 1-s2.0-S1572665715300278-main.pdf 1,6 МБ 10 сентября 2015 [V.Tyurin]

[1] The electrochemical approach to antioxidant activity assay of metal complexes with dipicolylamine ligand, containing 2,6-di-tert-butylphenol groups, based on electrochemical dpph-test / V. Y. Tyurin, A. Moiseeva, D. B. Shpakovsky, E. R. Milaeva // Journal of Electroanalytical Chemistry. — 2015. — Vol. 756. — P. 212–221. The novel electrochemical approach to antioxidant activity assay based on the reaction with stable radical 2,2´-diphenyl-1-picrylhydrazyl (DPPH) monitored by the rotating disk electrode (RDE) method was developed. This method has advantages in comparison with usual spectrophotometrical assay since it can be applied to colored compounds and in a wide range of concentrations. The electrochemical behaviour of Co(II), Mn(II), Fe(II), Cu(II), Zn(II), Ni(II) complexes with di-(2- picolyl)amine ligand L(1) containing antioxidant 2,6-di-tert-butylphenol pendant was studied by cyclic voltammetry (CV), and their radical scavenging properties were examined using the electrochemical DPPH-test. CV curves for these compounds contain the peaks of ligand and metal oxidation/reduction. The possible schemes of redox transformations were proposed. It was shown that the antioxidant capacity of these complexes depends strongly upon their redox properties, and the metal nature plays key role. Thus, the Co(II), Zn(II), Ni(II) complexes are less active than free ligand. But the easily oxidized Fe(II) complex shows high antioxidant activity which is comparable with the efficiency of the well-known antioxidant Trolox. In this case the synergetic antioxidant effect is observed due to the presence of an essential organic radical scavenger and redox-active metal. The feasible mechanism of antioxidant activity is discussed. [ DOI ]

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