ИСТИНА

Cagelike metallasilsesquioxanes is a fast growing class of metallacomplexes with attractive (supra)molecular architectures and valuable properties [1-2]. Lecture will present novel approaches to Cu-, Mn-, Fe-, Ln-silsesquioxanes and their complexes with auxiliary N,N-, N,O-, O,O-ligands. Noncovalent mechanisms leading to intriguing aggregation of metallasilsesquioxane coordination polymers will be discussed as well. Functionality of metallsilsesquioxanes (photophysics, magnetism, catalysis) will be shown. Acknowledgements: This work was funded by RSF (project 22-13-00250) References: [1] M. M. Levitsky, Y. V. Zubavichus, A. A. Korlyukov, V. N. Khrustalev, E. S. Shubina, A. N. Bilyachenko, J. Clust. Sci. 2021, 30, 1283. [2] A. N. Bilyachenko, N. Reis Conceição, M.F.C. Guedes da Silva, K.T. Mahmudov, G.B. Shul’pin, A.J.L. Pombeiro, Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes in Synthesis and Applications in Chemistry and Materials World Scientific, 2024