ИСТИНА

Nitrate complexes of transition metal with extended structure are quite exotic and so far little studied compounds. They demonstrate a variety of ways of binding magnetic ions with the formation of 1D-, 2D-, 3Ddimensional magnetic structures, in which interesting variants of superexchange interaction can be realized. We carry out systematic work in the field of synthesis of such compounds, the study of their crystal structure and magnetic properties. Here we demonstrate three new interesting examples of nitrate complexes involving Mn(II) (d5 hs), Co(II) (d7 hs) and Ni (d8 hs).