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Интеллектуальная Система Тематического Исследования НАукометрических данных |
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The stabilization of low-valent derivatives of Group 14 elements (M= Ge, Sn, Pb) may be achieved by application of groups capable to additional donation to the metal (thermodynamic stabilization). In this work the synthesis and structure of various polydentate ligands (N,N,N-, N,N,O-, O,N,O-) and “heavier” carbenes based on them (germylenes, stannylenes, plumbylenes) is investigated. Furthermore, application of the carbenes obtained as ligands for metal complexes (Pd, Mo, W) is described.