ИСТИНА

Substrate-mediated self-assembly is a strategy which exploits surface effects for ordering nanostructures on solids making them suitable for the integration with modern planar technologies in chemical sensing, optics, molecular electronics and catalysis. Surface-directed assembly of molecules and nanosized objects offers a labile platform for tailoring solid surfaces with well-defined supramolecular and hybrid assemblies presenting various functionalities. Herein, we summarize our achievements in this field to discuss several examples enlightening the application of this concept for the fabrication of hybrid supramolecular structures: 1) hierarchically assembled “double planes” of non-polymerized nucleotides on the synthetic receptor templates, 2) ultrathin films of organic chromophores with plasmon-enhanced optical absorption 3) porphyrin-based metal-organic frameworks on 2D layered templates such as rare-earth layered hydroxide and graphene oxide , and 4) seeded crystallization of 1D supramolecular conducting wires assembled from double-decker phthalocyaninates.