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Интеллектуальная Система Тематического Исследования НАукометрических данных |
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Mechanism of the Isomerization and Metathesis of Alkanes over Mixed Binuclear Complexes of Aluminum and Cobalt Halidesдоклад на конференции
- Авторы: Шилина М.И., Жидомиров Г.М., Глориозов И.П.
- Международная Конференция (Конгресс) : 15th International Congress on Catalysis
- Даты проведения конференции: 2012
- Тип доклада: Устный
- Докладчик: Шилина М.И.
- Место проведения: Мюнхен, Германия, Germany
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Аннотация доклада:
Transformations of alkanes in the presence of Lewis acids are usually treated from the standpoint of the carbocation mechanism . In this work the alkyl mechanism of paraffin activation over such catalysts has been found basing on the low temperature IR- spectroscopic in situ studies and quantum-mechanical accounts. The pathways of the formation of isomerization and metathesis products over the mixed binuclear complexes of aluminum/cobalt halides were established. The key role of the complexes with metal-metal bond was found in the activation of the alkanes.
- Добавил в систему: Шилина Марина Ильинична