ИСТИНА

Pd/MOF-5-type sample prepared by co-precipitation of MOF-5 together with Pd nitrate with subsequent vacuum thermal treatment is active both in CO oxidation and in chlorobenzene hydrodechlorination, in contrast to the similar catalyst produced by supporting of Pd from nitrate after MOF-5 preparation with subsequent reduction with hydrazine. On the base of preliminary data such difference could be caused not only by the different nature of active Pd sites situated in the framework of MOF or on the surface, but also by the use of thermal vacuum treatment to clean MOF structure from the absorbed solvent, and by the difference in crystal structure and MOF-5 content in the samples.