IUPAC-NIST Solubility Data Series. 92. Metal Carbonates. Part 1. Solubility and Related Thermodynamic Quantities of Cadmium(II) Carbonate in Aqueous Systemsстатья
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Аннотация:This paper, devoted to cadmium(II) carbonate, is the first in a series dedicated to the
solubility of compounds relevant to mobility of metals in the environment. Here, we
present compilations and critical evaluation of the experimental solubility data for
cadmium(II) carbonate, otavite, in aqueous ternary and higher-order systems. The solubility
of cadmium(II) carbonate depends on temperature, carbon dioxide partial pressure,
pH, the presence of complexing ions, and ionic strength of the solution. Papers referring
to solubility of cadmium(II) carbonate have been published since 1901; the thorough
search of the literature in this field covered the period from 1901 through 2009. The
compilation of the available experimental data is introduced with a critical evaluation.
The evaluation of the experimental data considers the possible correlation between the
data obtained under similar experimental conditions of temperature, carbon dioxide
partial pressure, electrolyte, and ionic strength. Those experiments where the solid
phase was well identified and the interactions between the electrolyte and the dissolved
cadmium(II) ion were considered practically negligible were used to determine the
thermodynamic properties of the solid cadmium(II) carbonate. Recommended values
for the thermodynamic quantities are lgK
ps0 ¼6.1160.10, DfG(CdCO3, cr, 298.15
K)¼(674.3 60.6) kJ mol1, DfH(CdCO3, cr, 298.15 K)¼(752.260.8) kJ mol1,
S(CdCO3, cr, 298.15 K)¼(103.960.2) J K1 mol1. VC 2011 American Institute of
Physics. [doi:10.1063/1.3645087]