Water-Zeolite Interfaces for Controlling Reaction Routes in Fischer- Tropsch Synthesis of Alternative Fuels

Авторы: Mordkovich Vladimir Z., Sineva Lilia V.
Журнал: Current Catalysis
Том: 9
Номер: 1
Год издания: 2020
Издательство: Bentham Science Publishers
Местоположение издательства: Netherlands
Первая страница: 3
Последняя страница: 22
DOI: 10.2174/2211544709999200420072505
Аннотация: Background: The Fischer–Tropsch synthesis (FTS) remains an important process for motorfuel production from CO and H2. The composition of the FTS products (hydrocarbon mixtures) dependson the properties of a catalyst and on the process conditions.Summary: The introduction of zeolites into catalytic systems can alter the molecular weight distributionpaving the way to tailor-made fuels, as was revealed by recent research results produced in the laboratoriesworldwide. The AlO4 and SiO4 tetrahedrons, which constitute the zeolites, are able to transferelectrons and ions in a way, which makes water-zeolite interfaces capable of initiating active carboniumions. It was shown in a number of works that the water-zeolite interface plays a key role in divertingthe FTS from the classical route.Conclusion: This review gives a critical analysis of literature data on the role of water-zeolite interfaceson FTS cobalt catalysts and on the interactions of hydrophobic and hydrophilic zeolites with water
Добавил в систему: Мордкович Владимир Зальманович

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