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Thermodynamic functions of poly(trifluoromethyl)fullerenes C60(CF3)n, n=2-18, by isodesmic reaction's methodтезисы доклада Тезисы
- Авторы: Romanova N.A., Druzhinina A.I., Varuschenko R.M., Papina T.S., Luk'yanova V.A., Goryunkov A.A., Sidorov L.N.
- Сборник: Book of abstracts of International Conference “Advanced Carbon Nanostructures ACNS'2015”
- Тезисы
- Год издания: 2015
- Место издания: St. Petersburg
- Первая страница: 84
- Аннотация: Experimental investigations of thermodynamic properties of trifluoromethylfullerenes were significantly hampered by the fact that preparation of pure compounds in amounts required for thermodynamic studying is a rather difficult task. Nevertheless, the large-scale synthetic availability of S 6 -symmetrical C60(CF3)12 opens up possibility of its thermochemical studies and determination of thermodynamic functions of broad range of poly(trifluoromethyl)fullerenes by isodesmic reaction's method. Previously, we synthesized gramme-scale amount of S6-С60(CF 3)12 and determined its thermodynamic functions. Here we reported the enthalpy of formation and C–CF3 bond dissociation enthalpies , for the broad range of structurally characterized poly(trifluoromethyl)fullerenes C60(CF3)n , n=2–18, by method of isodesmic reactions.
- Добавил в систему: Горюнков Алексей Анатольевич